Well, General, the troposphere is in the realm of “macrostate statistics” such as I use, but a fundamental assumption of Kinetic Theory is that the dynamics of the molecules can be treated classically. Feel free to edit Wikipedia if you think otherwise.
Besides, warm gas rising on Uranus is not a fact of life (or no life) out there. There’s no significant incident solar radiation or internal energy reaching the base of its nominal troposphere where it’s hotter than here on Earth, even though nearly 30 times further from the Sun.
On Venus, when the Sun rises, most of its incident energy is absorbed by carbon dioxide in the colder upper half of the troposphere and above. Some of that now-warmer gas “falls” to the far hotter surface, and that’s how we can explain why the surface temperature rises by 5 degrees over the course of the 4-month-long Venus day.
Oh, and there’s no hot air rising in the outer 10Km of Earth’s crust where a borehole in Germany enabled temperature measurements that conformed with the expected gravito-thermal gradient.
You know, General, you really don’t have to teach me what climatologists teach their climatology students who teach their climatology students … I’ve spent thousands of hours learning about all the details of the hoax, so that I could be watertight in my book when debunking it..
So please keep your arguments to physics in which you hopefully have at least a pass degree in order to participate in this somewhat esoteric discussion of 21st century breakthroughs in thermodynamics and the physics of radiative heat transfer. Otherwise you’ll be out of your depth, as have been hundreds of climatologists I’ve debated over the last three or four years on several climate blogs.
For a very comprehensive analysis of the climatology conjecture that the Second Law can still apply to the “net” of two or more independent processes, see my peer-reviewed paper “Radiated Energy and the Second Law of Thermodynamics” published on several websites two years ago, and which you’ll easily find on Google.
Then consider the fact that the second law of thermodynamics states that “Every process occurring in nature proceeds in the sense in which the sum of the entropies of all bodies taking part in the process is increased.”
Notice the words “every process” (singular) and the word “proceeds” which rules out going backwards first before you go further forwards. Radiation does not have to be two-way. Just consider radiation from a colder atmosphere penetrating just below the surface of warmer water. Is it absorbed just below the surface like solar radiation (both visible and IR) can be down to 10 metres or more in the ocean thermoclines? If not, then why not, and what does happen?