Craters on the earth get eroded, hidden, filled in, etc. Yes, many can be discerned, But a meteor that leaves even a small crater can ruin your day. Much better to count the craters on the moon, then factor in relative areas of moon vs earth, age of moon. etc. The odds will still be low of course, but you’ll have a better number. And certainly a higher number.
As to your other point,for CO2, and pretty much everything else due to the industrial activity of man (leaving out agriculture for the moment) that has been added to the environment, we have barely 150 years of history, No natural releases of CFCs has ever been proposed, but CO2 has been a part of the atmosphere since about Day 4, so why assume an ill effect for a trace gas that has many natural sinks, which should moderate any change?