Climatereason, 8/25/14 @ 2:59 pm: I am doubtful about the ice core records for co2 values. They seem to have been at similar levels to today in the recent past but it is difficult to explore this aspect without people invoking Ernst Beck. tonyb
First and notwithstanding any other considerations, we can rely on the ice core data to debunk IPCC until IPCC retracts the data.
Second, the ice core data are certainly suspect when the ice age is shorter than the closure time. For Vostok, that means data are suspect if less than about 1000 years old, but the samples are about 1500 years apart. Other cites are not so lucky.
Third, the Vostok CO2 and air temperature records tend to confirm one another, under the assumption that the Antarctic air temperature follows the sea surface temperature. The confirmation comes from Henry’s Law and the shape of Henry’s Coefficient for CO2 in water.
Fourth, an apparent problem with ice core CO2 not matching MLO data has two origins. One is that the Keeling Curve is a manufactured curve with a reconstituted mean and variability, coupled with the fact that MLO is in the plume of major CO2 outgassing from the Eastern Equatorial Pacific, and the plume likely wanders across the island with the prevailing wind. MLO CO2 is a regional effect that IPCC erases by calibrating all stations to that “master time series”.
The second aspect is that the MLO samples data in one minute or less, while Vostok CO2 is open for over half a millennium or so. In other words, Vostok CO2 is heavily filtered compared to MLO, both being low pass filters, and the data would be rejected if the means of the two records matched. Did Ernst Beck take low pass filtering into consideration?